The Pfaffian of a skew-symmetric matrix is a square root of its determinant.
Let be a skew-symmetric -matrix with entries in some field (or ring) .
The Pfaffian is the element
where
runs over all permutations of elements;
is the signature of a permutation.
Let be the Grassmann algebra on generators , which we think of as a vector
Then the Pfaffian is the Berezinian integral
Pfaffians appear in the expression of certain multiparticle wave functions. Most notable is the pfaffian state of spinless electrons
where denotes the Pfaffian of the matrix whose labels are and is the filling fraction, which is an even integer. For Pfaffian state see
J.-G. Luque, J.-Y. Thibon, Pfaffian and hafnian identities in shuffle algebras, math.CO/0204026