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In perturbation theory, the Dyson series is a perturbative expansion of a unitary time evolution operator, , primarily employed in quantum field theory. While it is asymptotically divergent, the second-order deviation from experimental data is on the order of paradoxically making it the most empirically accurate prediction in all of physics. It is a starting point for the use of Feynman diagram?s.
The Dyson series is given as
where is a time-ordering operator and is the interaction portion of the Hamiltonian.
Applying to some initial quantum state , we have
.